Phosphorus nitrogen compounds Part 43 Syntheses, spectroscopic characterizations and antimicrobial activities of cis - and trans -N/O dispirocyclotriphosphazenes containing ferrocenyl pendant arms
Yazarlar (6)
Doç. Dr. Yasemin TÜMER Karabük Üniversitesi, Türkiye
Prof. Dr. Nuran Asmafiliz Ankara Üniversitesi, Türkiye
Öğr. Gör. Zeynel Kılıç Ankara Üniversitesi, Türkiye
Doç. Dr. Betül Aydın Gazi Üniversitesi, Türkiye
Prof. Dr. Leyla Açık Gazi Üniversitesi, Türkiye
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Molecular Structure (Q3)
Dergi ISSN 0022-2860 Dergi Bilgileri (2018)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 12-2018
Kabul Tarihi Yayınlanma Tarihi 01-12-2018
Cilt / Sayı / Sayfa 1173 / 1 / 885–893 DOI 10.1016/j.molstruc.2018.07.050
Makale Linki https://linkinghub.elsevier.com/retrieve/pii/S002228601830869X
UAK Araştırma Alanları
Anorganik Kimya
Özet
The cis- (5 and 6) and trans-dispiroferrocenylphosphazenes (7 and 8) containing ferrocenyl pendant arms were synthesized from the reactions of hexachlorocyclotriphosphazene, N3P3Cl6, with two equimolar amounts of the sodium salts of the ligands; [2-(N-ferrocenylmethylamino)-1-ethanoxide (1) and 3-(N-ferrocenylmethylamino)-1-propanoxide (2)]. The monospiroferrocenylcyclotriphosphazenes (3 and 4) were also isolated from the reaction mixtures as by-products. The characterizations of the new compounds (5–8) were elucidated using MS, FTIR and 1H, 13C and 31P NMR techniques. The molecular structure of 6 was established by X-ray crystallography. As expected, compounds 5, 6, 7 and 8 have two stereogenic P-atoms. The compounds 5 and 6 are likely to be in cis (meso) forms, whereas the compounds 7 and 8 are in trans (racemic) forms. Besides, the antimicrobial activities of the …
Anahtar Kelimeler
Antimicrobial activity | Chiral phosphazenes | Crystal structure | Dispiroferrocenylphosphazenes | Spectroscopy