Spectroscopic, structural and DFT studies of luminescent Pt(II) and Ag(I) complexes with an asymmetric 2,2′-bipyridine chelating ligand
Yazarlar (5)
Doç. Dr. İsmail YILMAZ Karabük Üniversitesi, Türkiye
Nursel Acar-Selçuki Ege Üniversitesi, Türkiye
Simon J. Coles University Of Southampton, İngiltere
Dr. Öğr. Üyesi Fatih Pekdemir Zonguldak Bulent Ecevit University, Türkiye
Abdurrahman Şengül Zonguldak Bulent Ecevit University, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Molecular Structure (Q3) | ||
| Dergi ISSN | 0022-2860 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2021 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-01-2021 |
| Cilt / Sayı / Sayfa | 1223 / 1 / 129271–0 | DOI | 10.1016/j.molstruc.2020.129271 |
| Makale Linki | https://hdl.handle.net/20.500.12628/26004 | ||
| UAK Araştırma Alanları |
Anorganik Kimya
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| Özet |
| A new unsymmetrically substituted 2,2′-bipyridine ligand, 5-methyl-5′-carbomethoxy-2,2′-bipyridine (L) was isolated from the dry distillation of the copper(II) complex, mono-aqua-bis(trans-5-methyl-pyridine-2-carboxylato-N,O)copper(II). The ligand was fully characterized. The spectroscopic and single-crystal X-ray diffraction (SCXRD) studies of the coordination compounds of the ligand with platinum(II) and silver(I); cis-Pt(L)Cl2 (1) and [Ag(L)2]PF6 (2), respectively are reported. In 1, the Pt centre coordinates to tertiary N atoms of the ligand and two chloride ions to form a neutral square-planar coordination sphere, while in 2, the Ag(I) centre is coordinated by two ligands through N atoms to generate a cationic flattened tetrahedron geometry in which two mean planes intersect each other at 50.93°. The pyridine rings are nearly coplanar as revealed by the torsion angle of N2-C7-C6-N1 1.32(5)°. In both complexes … |
| Anahtar Kelimeler |
| Bipyridine | DFT studies | Luminescence | Platinum | Silver | X-ray structures |
Science Direct
Spectroscopic, structural and DFT studies of luminescent Pt(II) and Ag(I) complexes with an asymmetric 2,2′-bipyridine chelating ligand
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 14 |
| Scopus | 13 |
| Google Scholar | 16 |