Spectroscopic, EPR, X-ray structural, and DFT studies of the complex compound of N-4-donor ligand with copper(II)
Yazarlar (4)
Doç. Dr. İsmail YILMAZ Karabük Üniversitesi, Türkiye
Nursel S. Acar
Ege Üniversitesi, Türkiye
Ege Üniversitesi, Türkiye
Simon J. Coles
University Of Southampton, İngiltere
University Of Southampton, İngiltere
Prof. Dr. Abdurrahman Şengül Zonguldak Bulent Ecevit University, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Molecular Structure (Q3) | ||
| Dergi ISSN | 0022-2860 Dergi Bilgileri (2020) | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | Türkçe | Basım Tarihi | 01-2020 |
| Cilt / Sayı / Sayfa | 1214 / 1 / 128204–0 | DOI | 10.1016/j.molstruc.2020.128204 |
| UAK Araştırma Alanları |
Anorganik Kimya
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| Özet |
| A new mononuclear neutral five-coordinate copper(II) coordination compound [Cu(L)(H2O)] (1) (L = 6,6′-bis(NH-benzimidazol-2-yl)-2,2′-bipyridine) was synthesized and characterized by IR, UV–Vis, EPR and LC-MS (APCI) analysis. The crystal structure was also determined by X-ray crystallography. In 1, the copper(II) center adopts a five-coordinate distorted square-pyramidal (SP) geometry in which the basal plane formed by four of the nitrogen atoms of the ligand while the apical position is occupied by the oxygen atom of the water molecule. The four Cu–N bond lengths are 1.987(4), 1.992(4), 2.020(5) and 2.027(4) Å, and the longest bond of the apical Cu−Ow is 2.234(4) Å. The ligand undergoes deprotonation upon coordination to the metal center and acts as a dianionic tetradentate chelate to form a neutral complex [CuN4O]. The X-band EPR data of 1 are in agreement with the crystallographic data … |
| Anahtar Kelimeler |
| Benzimidazole | Bipyridine | Copper | Density functional theory | EPR | Tetradentate |
Science Direct
Spectroscopic, EPR, X-ray structural, and DFT studies of the complex compound of N-4-donor ligand with copper(II)
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 7 |
| Scopus | 7 |
| Google Scholar | 7 |