| Yazarlar (2) |
Dr. Öğr. Üyesi Sedef ŞİŞMANOĞLU
Karabük Üniversitesi, Türkiye |
Erdem Buran
|
| Özet |
| Natural wastes and inorganic adsorbents are used for the removal of diazo dye Congo red (CR), which causes water pollution and is a carcinogen, from wastewater. Organic waste olive pulp (ZK), inorganic ZrO (Zr) and three different weight percent ZK/Zr (organic/inorganic) binary adsorbent systems prepared by ball-milling method were investigated for the effective removal of CR from wastewater. Characterization of both single and binary adsorbent systems were carried out by ATR/FTIR and SEM. According to the Langmuir isotherm, q values for ZK, Zr, 25ZK-75Zr, 50ZK-50Zr and 75ZK-25Zr at 45 °C were 588 mgg, 13 mgg, 46 mgg, 65 mgg and 84 mgg, respectively. According to Frumkin-Fowler-Guggenheim and Temkin isotherms, the adsorption heat was found to be exothermic for ZK and 75ZK-25Zr at all three temperatures, while it was found to be endothermic for Zr, 25ZK-75Zr and 50ZK-50Zr. It was observed that the ΔG° values calculated from the thermodynamic data were consistent with the values in the Flory-Huggings isotherm. According to the kinetic data, it was observed that all adsorbents except ZK obeyed the pseudo-first-order rate equation. It was shown by error calculations that the experimental data obeyed the Langmuir or Freundlich isotherms better. It was observed that a new and effective organic/inorganic adsorbent system could be obtained by adding ZK to ZrO for the removal of Congo red (CR) from water. |
| Anahtar Kelimeler |
| Adsorption | ZrO2 | Congo red | Binary adsorbent systems |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
| Dergi Adı | Scientific Reports |
| Dergi ISSN | 2045-2322 Wos Dergi Scopus Dergi |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Dergi Grubu | Q1 |
| Makale Dili | İngilizce |
| Basım Tarihi | 01-2025 |
| Cilt No | 15 |
| Sayı | 1 |
| Sayfalar | 2842 / 0 |
| Doi Numarası | 10.1038/s41598-024-83639-2 |
| Makale Linki | file:///C:/Users/Lenovo/Downloads/s41598-024-83639-2.pdf |
| Atıf Sayıları | |
| WoS | 1 |
| SCOPUS | 1 |
| Google Scholar | 1 |
